Precision measurements and computations of transition energies in rotationally cold triatomic hydrogen ions up to the midvisible spectral range.
نویسندگان
چکیده
First-principles computations and experimental measurements of transition energies are carried out for vibrational overtone lines of the triatomic hydrogen ion H(3)(+) corresponding to floppy vibrations high above the barrier to linearity. Action spectroscopy is improved to detect extremely weak visible-light spectral lines on cold trapped H(3)(+) ions. A highly accurate potential surface is obtained from variational calculations using explicitly correlated Gaussian wave function expansions. After nonadiabatic corrections, the floppy H(3)(+) vibrational spectrum is reproduced at the 0.1 cm(-1) level up to 16600 cm(-1).
منابع مشابه
به کاربردن تقریب دو حالته در تولید هیدروژن با فرود آمدن پروتون بر روی پوزیترونیوم
Although there is no experimental data available for antihydrogen formation following antiprotons impact on positroium atoms, as a charge transfer reaction, at incident energies which are suitable for antimatter high-precision spectroscopic studies, measurements were carried out for its charge-conjugate reaction i. e. hydrogen formation, by protons impact on positronium. In this study, a two-st...
متن کاملVibrationally and rotationally nonadiabatic calculations on H3+ using coordinate-dependent vibrational and rotational masses
Using the core-mass approach, we have generated a vibrational-mass surface for the triatomic H3+. The coordinate-dependent masses account for the off-resonance nonadiabatic coupling and permit a very accurate determination of the rovibrational states using a single potential energy surface. The new, high-precision measurements of 12 rovibrational transitions in the ν2 bending fundamental of H3+...
متن کاملروش جفت‌شدگی نزدیک دومرکزی در فرآیند انتقال بار
In the present work, the transition matrix elements as well as differential and total scattering cross-sections for positronium formation in Positron-Hydrogen atom collision and hydrogen formation in Positronium-Hydrogen ion collision, through the charge transfer channel by Two-Centre Close-Coupling method up to a first order approximation have been calculated. The charge transfer collision is ...
متن کاملHydrogen Abstraction Reaction of Hydroxyl Radical with 1,1-Dibromoethane and 1,2-Dibromoethane Studied by Using Semi-Classical Transition State Theory
The hydrogen abstraction reaction by OH radical from CH2BrCH2Br (R1) and CH₃CHBr2 (R2) is investigated theoretically by semi-classical transition state theory. The stationary points for both reactions are located by using ωB97X-D and KMLYP density functional methods along with cc-pVTZ basis. Single-point energy calculations are performed at the QCISD(T) and CCSD(T) levels of theory with differe...
متن کاملTechnical guide to Set Up a Spectral Solar Direct Normal Irradiance Permanent Station: Study Area- Hannover, Germany
The spectral Direct Normal Irradiance (SDNI) is a basic radiometric quantity from which many other quantities can be derived. It provides not only information about the spectral and distribution of the direct solar radiation reaching a particular location. Accurate knowledge about the spectral direct irradiance shall enable us to gain new scientific results in the: determination of cloud effect...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 108 2 شماره
صفحات -
تاریخ انتشار 2012